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We have prepared and tested laboratory scale monoliths wash-coated with 10, 20 and 30 wt% of either CeO2 or Ce.75Zr.25O2 (remainder is alumina). Wet impregnation was used to load the wash-coated monoliths with 50g/ft Pt:Rh at a 5:1 ratio. The catalyst were aged at temperatures between 825°C and 950°C using a cycled redox aging. The catalysts were then tested in a full-feed simulated exhaust laboratory reactor with air-to-fuel ratio (A/F) perturbations (frequencies at 1 and 3 Hz and amplitudes up to +/- 0.8 A/F). Even the lowest loading of Ce.75Zr.25O2 outperformed all three loadings of CeO2 over a full range of reaction temperatures, A/F perturbations, and catalyst space velocity (SV). Our data indicates that the ceria-zirconia catalysts can tolerate cycled redox aging at sustained bed temperatures at least 25°C higher (∼925°C vs. < 900°C) than can ceria. For the CeO2 catalysts aged at or above 900°C we observed an inverse correlation of catalyst activity to CeO2 loading.

The current extensive revisitation of the application of gasoline direct-injection to automotive, four-stroke, spark-ignition engines has been prompted by the availability of technological capabilities that did not exist in the late 1970s, and that can now be utilized in the engine development process. The availability of new engine hardware that permits an enhanced level of computer control and dynamic optimization has alleviated many of the system limitations that were encountered in the time period from 1976 to 1984, when the capabilities of direct-injection, stratified-charge, spark-ignition engines were thoroughly researched. This paper incorporates a critical review of the current worldwide research and development activities in the gasoline direct-injection field, and provides insight into new areas of technology that are being applied to the development of both production and prototype engines.

A novel approach is presented to the problem of robust control strategy for an Exhaust Gas Recirculation (EGR) system. Modeling issues and controller design for an electric valve are presented. Robustness is one of the main issues due to nonlinearities (hysteresis, friction), computational time delays, and the effects of complex exhaust gas dynamics. A high level of noise, due to engine vibrations, makes the input-output model identification very difficult. We use a special windowing technique to successfully complete the identification. It was found that a good approximation of the system dynamics consists of a first order transfer function with a time delay whose parameters depend on the operating conditions (engine load, r.p.m.). Thus, the nonlinear effects of friction and hysteresis are replaced, for the purpose of control design, by variable gain, time delay, and time constant of the linear model.

Combustion instability is investigated during the cold starting of a single cylinder, direct injection, 4-stroke-cycle, air-cooled diesel engine. The experiments covered fuels of different properties at different ambient air temperatures and injection timings. The analysis showed that the pattern of misfiring (skipping) is not random but repeatable. The engine may skip once (8-stroke-cycle operation) or twice (12-stroke-cycle operation) or more times. The engine may shift from one mode of operation to another and finally run steadily on the 4-stroke cycle. All the fuels tested produced this type of operation at different degrees. The reasons for the combustion instability were analyzed and found to be related to speed, residual gas temperature and composition, accumulated fuel and ambient air temperature.